With the addition of Montenegro on 28 June 2006, there are 192 United Nations member states, including virtually all internationally-recognized independent states.
The United Nations Charter outlines the rules for membership:
Membership in the United Nations is open to all other peace-loving states which accept the obligations contained in the present Charter and, in the judgment of the Organization, are able and willing to carry out these obligations.
The admission of any such state to membership in the United Nations will be effected by a decision of the General Assembly upon the recommendation of the Security Council.
—United Nations Charter, Chapter 2, Article 4, http://www.un.org/aboutun/charter/
Group of 77 (G77)
Member states of G77
The Group of 77 at the UN is a loose coalition of developing nations, designed to promote its members' collective economic interests and create an enhanced joint negotiating capacity in the United Nations. There were 77 founding members of the organization, but the organization has since expanded to 130 member countries. The group was founded on 15 June 1964 by the "Joint Declaration of the Seventy-Seven Countries" issued at the United Nations Conference on Trade and Development (UNCTAD). The first major meeting was in Algiers in 1967, where the Charter of Algiers was adopted and the basis for permanent institutional structures was begun
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